Don't pop the sucker, the blister forms for a reason, to help with healing. If you do, it will take a bit longer to heal up and the scar could end up being worse and could lead to the possibility of a pretty nasty infection. But if you do go ahead and pop it just make sure to keep that fucker clean as you can.
I have had my share of these damn burns, and my best advice is to just keep the area clean. Put some ointment on it, antibacterial stuff and what not, and try your best not to screw around with it. Just give it time.