My 2 cents. Assuming the vehicle in question is the same burnt copper red as shown in the example.
Red and Black combo will make your wheels fade into the wheel well. If you are going for a stealth look where the wheel will fade into the background in turn, making the car itself the star of the show then I would go with that. It is very unlikely that black wheels will catch much (if any) attention due to how colors catch people's eye. You could shine up the black and make it glossy, but that still would not help bring attention to the average person. Black will almost always fad into the back of our minds and not be the "eye catcher" most people think it can be. In some cases, yes black can catch your eye but not in this example due to the color of the example vehicle.
Red and silver combo will make the wheels pop more which have a better chance to A: complement the car's appearance or B: become the eye catcher which will bring someone's eyes to your vehicle. The advantage of the silver/chrome option is that it will bring the most overall attention to your car which can make the wheel or the car the star of the show. There is also a downside to this option as well. At times, the silver/chrome option could also damage the appearance by taking to much attention from other aspects of the car. In addition, if you choose an ugly or horrible design then people will only remember that when they think of your car. Choose wisely when picking something that is silver or shiny because it can attract unwanted attention.
IMO, I would go with the silver. I have never been a fan of blacked out wheels, but at the end of the day I would say buy what makes you happy. What do you see yourself looking at when you envision your car in the morning?
The again, there is always this option...
¿por qué no los dos?